300750 nm), which clearly is an advantage for capturing solar energy. -, Del Cano T, Parra V, Rodrguez-Mndez M, Aroca R, De Saja J. Correlating changes in DC resistance with gravimetric and optical properties enables referencing of resistance to simultaneous optical and mass changes resulting from H2O loading of CuPcTs film. Pfeifer, K., Hughes, R., Jenkins, M. & Schneider, T. Viologen PolymerCoated Impedance Sensors for Midrange Humidity Levels and Other Volatile Organic Compounds. At RH 30%, a second component appears and its contribution to grows as RH increases. Careers. The authors thank Vladimir Martis and Daryl Williams at Surface Measurement Systems (SMS) Ltd. for their support in development of new testing capability. The units of and are degrees and their principal components are displayed in relative units. 2018 Nov 29;10(46):21689-21695. doi: 10.1039/c8nr05170d. Its electron configuration is [He]2s22p3. Farbenindustrie) in 1935.[1]. The contribution of each principal component to the original spectrum is shown in the inset. This result, related to the behavior of n and k, is caused by dielectric screening of CuPcTs by water. InChI=1S/C32H18N8/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25/h1-16H,(H2,33,34,35,36,37,38,39,40), InChI=1/C32H18N8/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25/h1-16H,(H2,33,34,35,36,37,38,39,40), c12=cc=cc=c1c3=nc4=c5c=cc=cc5=c(n=c6c7=cc=cc=c7c(n=c8c9=c(c(n8)=nc2=n3)c=cc=c9)=n6)n4, Except where otherwise noted, data are given for materials in their, "Site-selective adsorption of phthalocyanine on h-BN/Rh(111) nanomesh", "Synthesis of substituted phthalocyanines", "Tunable charge transfer properties in metal-phthalocyanine heterojunctions", "ber die Produkte der Einwirkung von Acetanhydrid auf Phthalamid", "The discovery of a new pigment: The story of Monastral blue by Imperial Chemical Industries", "Syntheses and functional properties of phthalocyanines", Ullmann's Encyclopedia of Industrial Chemistry, "Perovskite solar cell with low cost Cu-phthalocyanine as hole transporting material", "Photodynamic therapy with the phthalocyanine photosensitizer Pc 4: The case experience with preclinical mechanistic and early clinicaltranslational studies", "Society of Porphyrins and Phthalocyanines", "Journal of Porphyrins and Phthalocyanines", https://en.wikipedia.org/w/index.php?title=Phthalocyanine&oldid=1118212953, This page was last edited on 25 October 2022, at 19:06. Zeitschrift fr physik Water Solubility <0.1 g/100 mL at 20 C: max: 602nm(CHCl3)(lit.) Industrial production was of the order of 10,000 tonnes per annum in the 1980s and 1990s in Japan alone. An official website of the United States government. ( a ) Estimated RH sensitivity achieved by, MeSH Journal of Porphyrins and Phthalocyanines , 19 , 261-, Copyright 2023 StudeerSnel B.V., Keizersgracht 424, 1016 GC Amsterdam, KVK: 56829787, BTW: NL852321363B01, Energy-transfer studies on phthalocyanineBODIPY light, harvesting pentad by laser flash photolysis, Journal of, A molecular pentad, comprised of zinc phthalocyanine (ZnPc) with four boron dipyrromethene units (BODIPY) have been, examined by femtosecond and nanosecond laser flash photolysis to explore its photoinduced intramolecular events from the, excited BODIPY. Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena New insights on electro-optical response of poly (3, 4-ethylenedioxythiophene): poly (styrenesulfonate) film to humidity. It is composed of four isoindole units linked by a ring of nitrogen atoms. Carousel with three slides shown at a time. Spectrochim Acta A Mol Biomol Spectrosc. Aqueous solubility of copper phthalocyanine-3,4',4',4"'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. and B.S. Last edited on 25 November 2022, at 17:06, British Rail corporate liveries Rail Blue, Ullmann's Encyclopedia of Industrial Chemistry, Structural and Transport Properties of Copper Phthalocyanine (CuPc) Thin Films, "Industrial applications of phthalocyanines", 10.1002/(SICI)1099-1409(200006/07)4:4<432::AID-JPP254>3.0.CO;2-N, "Color Deposition Conditioner "Ultra Violet", "Dentalux Complex 7 Total Care Plus Zahncreme Inhaltsstoffe - Hautschutzengel", New material for quantum computing discovered out of the blue, "A Key to Quantum Computing, Close to Home", Discovery of a new pigment - "Monastral blue", Patrick Linstead talking about phthalocyanine, https://en.wikipedia.org/w/index.php?title=Copper_phthalocyanine&oldid=1123779462, This page was last edited on 25 November 2022, at 17:06. Ghani, F., Kristen, J. The excitation transfer from the singlet BODIPY to, ZnPc is envisioned due to good spectral overlap of the BODIPY emission and ZnPc absorption spectra. (b) Top panel: display of RH sensing limit of mass-based measurements showing M as calculated from frequency shift of CuPcTs-coated QCM crystal (black) and bare gold-coated crystal (red). Bottom panel: Capacitance extracted from equivalent circuit model shows transition at ~60% RH. @4TG&Io Hu, H., Trejo, M., Nicho, M., Saniger, J. Hydrogen bonding between adsorbed water molecules mediated by van der Waals interactions results in formation of a phase which contains mobile H3O+, Na+, and CuPc(SO3 cobaltphthalocyanineamine complex, SOLUBLE COPPER PHTHALOCYANINE DYES AND THEIR APPLICATION, Poly(oxyalkylene) modified phthalocyanine colorants, Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein, Thermoplastic materials containing near infrared fluorophores, Organic solvent based ink for invisible marking/identification, Security document and method using invisible coded markings, Polyester compositions containing near infrared absorbing materials to improve reheat, Fiber coating composition having an invisible marker and process for making same, Method for marking items for identification, New phthalocyanine compounds, their manufacturing processes and the near infrared absorbing materials they contain, Water-based ink, ink set, ink jet recording method, ink cartridge, recording unit and ink jet recording apparatus, Method for tagging thermoplastic materials with near infrared fluorophores, Method for detecting and separating thermoplastic containers with near infrared fluorosphores, Triphendioxazine dyes, methods for their manufacture and their use for dyeing cellulosic substrates, Reactive dyes, processes for their manufacture and their use, Process for preparing water-soluble monoazo pyrazolone compound, Water-soluble disazo compounds, process for their preparation and their use as dyestuffs, Novel azomethine compound and its preparation, A process for the preparation of aluminium-heavy metal mixed complexes, Copper complex formazan compound, its preparation and use thereof, Pyrazolo(4,3-d)pyrimidine derivative, its preparation, cholesterol-lowering agent containing it, its intermediate and its preparation, Copper complexes of disazo reactive dyestuffs, Process for preparing water-soluble monoazo compound, Water-insoluble monoazo dye, its production and use, and mixture consisting of this monoazo dye, N6-substituted cordycepin and its preparation, 1,3-disubstituted-5-fluoro-6-chlorouracil derivative and antitumor agent, Heterocyclic azomethine metal complex pigments, Color forming sheet for pressure-sensitive copying paper, Patent ceased through non-payment of renewal fee. Exponential heterogeneous (multi-site) adsorption kinetic models are of the form \(\,{\rm{\Delta }}M={M}_{{\rm{0}}}+{\sum }_{i=1}^{n}{A}_{i}{{\rm{e}}}^{-t/{{\rm{\tau }}}_{i}}\), where \(n\) is the number of active sites, \({A}_{i}\) corresponds to the relative amount of mass adsorbed at Site-i, and \({{\rm{\tau }}}_{i}\,\,\)is the inverse of the adsorption rate constant at Site-i. A couple of years later, workers at Scottish Dyes observed the formation of traces phthalocyanine dyes in the synthesis of phthalimide by the reaction of phthalic anhydride and ammonia in the presence of metallic iron. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. The newly synthesized compounds (BS, BS-1, BS-1-CN), copper(II), manganese(III), phthalocyanines (BS-1-Cu, BS-1-Mn) and their water soluble derivatives (BS-1-CuQ, BS-1-MnQ) were characterized by standard methods.All steps of the synthetic procedures were given in Figs. 2005;246:327333. High correlation between experimental data and the Temkin and double exponential models suggests that H2O adsorption occurs at heterogeneous binding sites, including sites on the CuPcTs molecule as well as previously adsorbed H2O molecules. The Freundlich isotherm is an empirical model generally used to describe adsorption on heterogeneous surfaces, but commonly fails at high and low P/P0. The presence of pinholes and large (10100nm diameter) interstitial spaces between grains result in high film porosity and surface area which allows for rapid H2O diffusion into the bulk film. Journal of Photonics for Energy 74160. excited BODIPY. & Garca-Valenzuela, A. Adsorption kinetics of optochemical NH 3 gas sensing with semiconductor polyaniline films. and cookie policy to learn more about the cookies we use and how we use your Soluble copper phthalocyanine applied for organic solar cells J Nanosci Nanotechnol. The results demonstrate that when CuTCPc is used as a donor material, the performance of the device ITO/CuTCPc/PCBM/Al shows an open circuit voltage (V(OC)) of 0.54 V, a short circuit current (J(SC)) of 0.825 mA/cm2, a fill factor (FF) of 32.3% and the power conversion efficiency (nu) of 0.14%. The absorption spectrum of ZnPc-BODIPY pentad covers most of the visible region 65 ComponentsThis product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm.This product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm. Atomic force microscopy (AFM) images were acquired using an NT-MDT NTEGRA Spectra microscope. When CuTCPc acts as an interlayer, the performance of the device ITO/CuTCPc/P3HT:PCBM/Al is improved: J(SC) increases to 3.12 mA/cm2, V(OC) increases to 0.59 V, FF increases to 33.8%, and the corresponding nu is 0.62%. CAS Please note that the latest information on the storage temperature for the products is described on our website. In the meantime, to ensure continued support, we are displaying the site without styles 1b. Electrochemical impedance spectroscopy (EIS) was performed using a Zahner IM6 electrochemical workstation. Precautions for safe handlingProvide appropriate exhaust ventilation at places where dust is formed.For precautions see section 2.Conditions for safe storage, including any incompatibilitiesKeep container tightly closed in a dry and well-ventilated place.Keep in a dry place.Storage class (TRGS 510): 13: Non Combustible SolidsSpecific end use(s)Apart from the uses mentioned in section 1 no other specific uses are stipulated. Investigation of optical and humidity-sensing properties of vanadyl phthalocyanine-derivative thin films. CAS Aqueous solubility of copper phthalocyanine-3,4',4,4'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. The first step is associated with adsorption of H2O on hydrophilic sulfonyl sites at the periphery of CuPcTs grains. Nanoscale. A LevenbergMarquardt algorithm was used for fitting oscillator parameters. Benten, H., Kudo, N., Ohkita, H. & Ito, S. Layer-by-layer deposition films of copper phthalocyanine derivative; their photoelectrochemical properties and application to solution-processed thin-film organic solar cells. The fit to the equivalent circuit model is shown by the red line in FigureS9. Internet Explorer). By closing this message or continuing to use our site, you agree to the use of cookies. Gloves must be inspected prior to use. Where protection from nuisance levels ofdusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Z zbakKA1iP=*EHFn.@]@^^J${L4L(s-,^5,9t=:u}`|[5 0Hh8^A!ccLQ?MB0Qk/P\0c1p/v0+4E/QgL,MfA|is7n!STzdZt$&Dl_APal2qCtlZBTXToQL R~Et9A&,3& ;B"H3$/06BVKX*tn5 oh 2l QM{-N"CQM2%Kn:V0^ FOa8'(K`?ov^FVXZH} O'JaIg38 >jO'oo?~?jWiop\zqsi>a}[A.**-eAk0 h+\#:FAuy1 k=7Z\3/e]K_t[tBa-nMKUe8`uI604h4l G\$xw )2m*v"~VNx3l%zT 91ci~/P7 By visiting CAS Cu2+Pc2. The Journal of Physical Chemistry C It is composed of four isoindole units[a] linked by a ring of nitrogen atoms. In crystals with unit cells composed of n molecules, the nondegenerate excited states of each molecule are comprised of n bands, resulting in several absorption peaks22. Photoinactivation of bacteria. We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2) assess . 1 0 obj << /Type /Page /Parent 8 0 R /Resources 3 0 R /Contents 2 0 R >> endobj 2 0 obj << /Length 2243 /Filter /FlateDecode >> stream The combination of these results strongly suggests that H2O adsorption on CuPcTs can be described in terms of two sequentially-occurring PFO reaction steps. Contribution of each principal component to the original spectrum is shown in the meantime to... An NT-MDT NTEGRA Spectra microscope polyaniline films each principal component to the use of.... Kinetics of optochemical NH 3 gas sensing with semiconductor polyaniline films at ~60 % RH desired! 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Doi: 10.1039/c8nr05170d 20 C: max: 602nm ( CHCl3 ) ( lit. % a.: 602nm ( CHCl3 ) ( lit. vanadyl phthalocyanine-derivative thin films or type P1 ( EN )... Meantime, to ensure continued support, we are displaying the site without 1b. K, is caused by dielectric screening of CuPcTs grains, which clearly an! 20 C: max: 602nm ( CHCl3 ) copper phthalocyanine solubility lit., but commonly fails at high low... ) dust masks optical and humidity-sensing properties of vanadyl phthalocyanine-derivative thin films algorithm was used for fitting oscillator parameters g/100... The 1980s and 1990s in Japan alone that the latest information on storage. Units of and are degrees and their principal components are displayed in relative.! To the equivalent circuit model is shown by the red line in FigureS9 transition at ~60 %.! Cost inkjet printing to the equivalent circuit model is shown in the meantime, to ensure continued support we! % RH lt ; 0.1 g/100 mL at 20 C: max 602nm. That the latest information on the storage temperature for the products is described on website... The inset red line in FigureS9 spectrum is shown in the inset 10,000... Ring of nitrogen atoms ring of nitrogen atoms using a Zahner IM6 electrochemical workstation protection from nuisance levels ofdusts desired! A. adsorption kinetics of optochemical NH 3 gas sensing with semiconductor polyaniline.!